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Conformational study of 5 leucine enkephalin by laser raman spectroscopy

, : Conformational study of 5 leucine enkephalin by laser raman spectroscopy. International Journal of Peptide & Protein Research 16(3): 173-182

The Raman spectrum of [Leu5]-enkephalin in the solid state indicates the presence of a type I'.beta. bend, in agreement with X-ray data. In solution, this molecule takes on different conformations in different solvents. In deuterated dimethyl sulfoxide, it forms a .beta.-bend structure; in H2O it exists as an ensemble of conformations.


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