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Enzymatic interesterification in supercritical carbon dioxide

, : Enzymatic interesterification in supercritical carbon dioxide. Agricultural & Biological Chemistry 52(6): 1541-1550

An enzymatic reaction with supercritical carbon dioxide (SCCO2) as the reaction medium was investigated. Lipase could catalyze the batch type reaction of hydrolysis and interesterification (acidolysis) in SCCO2 at and 29.4 MPa. The time course of interesterification was influenced by the waer content was well as by the kind of reaction medium. The initial velocities of hydrolysis and interesterification were greater in SCCO2 than in n-hexane when the water content increased. A part of this difference in reaction velocity was suppossed to be due to water, a modifier of the solvent, the solubility of which in SCCO2 was estimated to be a hundred times that in n-hexane.


DOI: 10.1080/00021369.1988.10868888

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