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Total synthesis of racemic 8 15 diisocyano 11 20 amphilectene


, : Total synthesis of racemic 8 15 diisocyano 11 20 amphilectene. Journal of Organic Chemistry 54(7): 1483-1484

With 2-(methoxycarbonyl)-3-methylcyclohexanone and (E)-1-(tert-butyldimethylsiloxy)-6-iodo-3-(trimethylstannyl)-2-hexene as starting materials, the structurally novel, antimicrobial diterpenoid (.+-.)-8,15-diisocyano-11(20)-amphilectene (2) was synthesized in 20 steps.

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