+ Resolve Article
+ Follow Us
Follow on FacebookFollow on Facebook
Follow on TwitterFollow on Twitter

+ Translate
+ Subscribe to Site Feed
GeoScience Most Shared ContentMost Shared Content

Packing of ruthenium sensitizer molecules on mostly exposed faces of nanocrystalline TiO2: Crystal structure of (NBu4+)2(Ru(H2tctterpy)(NCS)3)2-cntdot0.5 DMSO

, : Packing of ruthenium sensitizer molecules on mostly exposed faces of nanocrystalline TiO2: Crystal structure of (NBu4+)2(Ru(H2tctterpy)(NCS)3)2-cntdot0.5 DMSO. Applied Organometallic Chemistry 16(11): 635-642

An X-ray crystal study of the new 'black dye' sensitizer tri(thiocyanato)(4,4',4"-tricarboxy-2,2':6',2"-terpyridine)ruthenium(II) is reported. In the crystal, strong hydrogen bonds form chains of ruthenium complex dianions with the OcntdotcntdotcntdotO distances of 2.48-2.54 ANG. From the molecular geometry of the dianions, structural models of their close packing on the (101) and (001) crystal surfaces of TiO2 (anatase) have been built.


Other references

Stepkowska E.T.; Nesteruk M., 1978: Mineralogical and sorption study of the clay soil from Belchatow. Archiwum Hydrotechniki 25(2): 261-274

Chapuis, G., 1984: Vascular lesions associated with knee injuries. Helvetica Chirurgica Acta 51(5): 575-580

Broughton, A.C.; Secord, D.C.; Scott, G.W., 1977: Effects of adrenergic stimulation on the choledochoduodenal sphincter mechanism. The object of this study was to access the effects of systemic bolus injections of epinephrine and of norepinephrine upon the sphincter at the choledochoduodenal junction in the cat and the dog. The bile duct was transected and the downstream segm...

Leeds, H.S.; Richards, E.P., 2008: Legal issues in accommodating the Americans with disabilities act to the diabetic worker. Journal of Legal Medicine 29(3): 271-283

Principi, E.A., 1985: A skeleton only clad with skin: the medico-legal aspects of anorexia nervosa. Legal Medicine: 108-116

Hirakura, T.; Yasugi, K.; Nemoto, T.; Sato, M.; Shimoboji, T.; Aso, Y.; Morimoto, N.; Akiyoshi, K., 2010: Hybrid hyaluronan hydrogel encapsulating nanogel as a protein nanocarrier: new system for sustained delivery of protein with a chaperone-like function. Novel hybrid hyaluronan (HA) hydrogel encapsulating nanogels was designed for sustained delivery of protein. HA modified with 2-aminoethyl methacrylate was cross-linked via Michael addition in the presence of cholesteryl group-bearing pullulan (CH...

Mahalingam, G.; Meyers, B.C., 2010: Computational methods for comparative analysis of plant small RNAs. Small RNAs play an important role in plant development, stress responses, and epigenetic regulation, primarily through their role in transcriptional and post-transcriptional silencing of specific target genes and loci. Most if not all plants utili...

Dzhanga, A.A.; Barabanshchikov, V.I., 1993: Cloning of Bacillus subtilis chromosomal fragment suppressing sbc B mutation of Escherichia coli. A. 3.54 kb chromosomal fragment of Bacillus subtilis was cloned on the plasmid pBluescript SK(+). The fragment suppresses the repair deficiency of the sbc B15 mutation of Escherichia coli. It is shown that the B. subtilis gene of exonuclease ! is...

Ibekwe, T.S.; Kokong, D.D.; Ngwu, B.A.; Akinyemi, O.A.; Nwaorgu, O.G.; Akang, E.E., 2007: Nasal septal teratoma in a child. Teratoma is a rare developmental neoplasm that arises from totipotential tumor stem cells. Head and neck teratomas constitute about 10% of all cases. Only two cases of mature teratoma of the nasal septum have previously been documented in the worl...

Pinger, R.R.; Jr.; Rowley, W.A., 1972: Occurrence and seasonal distribution of Iowa mosquitoes. Catches of mosquitos in New Jersey light-traps operated in 7 widely separated counties of Iowa during 1969-70 are discussed, and seasonal changes in numbers caught are shown in graphs. Altogether, 79 757 mosquitos comprising 34 species were caught...