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Benzoxepine esters as precursors of the wound-activated chemical defence of Mycena galopus

, : Benzoxepine esters as precursors of the wound-activated chemical defence of Mycena galopus. European Journal Of Organic Chemistry: 1187-1194

The native precursors <i>E/Z</i>-1a to <i>E/Z</i>-1e and 2a-2e of the anti-fungally active benzoxepines <i>E/Z</i>-1 and 2 have been isolated from intact fruiting bodies of <i>Mycena galopus</i>. These precursors turned out to be fatty acid esters of the benzoxepines (pterulones) <i>E/Z</i>-1 and 2.


DOI: 10.1002/ejoc.200700812

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