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Electron ionization induced fragmentation of 4-hydroxychalcone derivatives


, : Electron ionization induced fragmentation of 4-hydroxychalcone derivatives. Rapid Communications in Mass Spectrometry 16(6): 634-637

Analysis of tingenone and tingenol quinonemethide triterpenes was made by gas chromatography/mass spectrometry (GC/MS) of their trimethylsilyl (TMS) ethers. An extra TMS group, in addition to those predicted from the known structures, is added to these compounds during the derivatization process. The electron impact mass spectra showed base peaks at m/z 549 and 623, respectively, for the TMS derivatives of tingenone and tingenol, and electrospray (ES) and collision-activated dissociation (CAD) studies indicate that these ions correspond to losses of a methyl group from the derivatives studied. A mechanism, based on ES-MS/MS studies, is suggested for the derivatization and fragmentation pattern.

US$19.90

PMID: 11870902

DOI: 10.1002/rcm.596


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