+ Resolve Article
+ Follow Us
Follow on FacebookFollow on Facebook
Follow on TwitterFollow on Twitter

+ Translate
+ Subscribe to Site Feed
GeoScience Most Shared ContentMost Shared Content

Multidimensional femtosecond correlation spectroscopies of electronic and vibrational excitations

, : Multidimensional femtosecond correlation spectroscopies of electronic and vibrational excitations. Annual Review of Physical Chemistry 51: 691-729

Femtosecond visible and infrared analogues of multiple-pulse nuclear magnetic resonance techniques provide novel snapshot probes into the structure and electronic and vibrational dynamics of complex molecular assemblies such as photosynthetic antennae, proteins, and hydrogen-bonded liquids. A classical-oscillator description of these spectroscopies in terms of interacting quasiparticles (rather than transitions among global eigenstates) is developed and sets the stage for designing new pulse sequences and inverting the multidimensional signals to yield molecular structures. Considerable computational advantages and a clear physical insight into the origin of the response and the relevant coherence sizes are provided by a real-space analysis of the underlying coherence-transfer pathways in Liouville space.


PMID: 11031297

DOI: 10.1146/annurev.physchem.51.1.691

Other references

Berges, H.; Checroun, C.; Guiral, S.; Garnerone, A.M.; Boistard, P.; Batut, J., 2002: A glutamine-amidotransferase-like protein modulates FixT anti-kinase activity in Sinorhizobium meliloti. Finan, Turlough M [Editor, Reprint Author], O'Brian, Mark R [Editor], Layzell, David B [Editor], Vessey, J Kevin [Editor], Newton, William [Editor] Nitrogen fixation: Global perspectives : 430

Edis, M., 1989: The interview. 2. Games people play. Nursing Times 85(26): 45-47

Brase, G.L., 2002: Ecological and evolutionary validity: comments on Johnson-Laird, Legrenzi, Girotto, Legrenzi, and Caverni's (1999) mental-model theory of extensional reasoning. The mental-model account of naive probabilistic reasoning by P. N. Johnson-Laird, P. Legrenzi, V. Girotto, M. S. Legrenzi, and J.-P. Caverni (1999) provides an opportunity to clarify several similarities and differences between it and ecological r...

Brown, C.R.; Brown, M.B.mberger, 2000: Weather-mediated natural selection on arrival time in cliff swallows. An unusually long period of cold weather in May 1996 caused extensive mortality among insectivorous cliff swallows (Petrochelidon pyrrhonota) in the northern and central Great Plains. We analyzed how viability selection affected spring arrival tim...

Tcoske, Z.; Lclszlcd, K.; Pintye-Hcddi, K., 2007: Connection Between Surface Properties, Specific Surface Area and Component Distribution of Binary Mixtures of Corn Starch and Metronidazole. Knowledge of the surface properties of pharmaceutical solids and excipients is of great significance for an understanding of the interactions between the particles of powders and powder mixtures [1, 2] and the accessories of the equipment [3] in t...

Xu, J.; Li, Y.; Wang, Y.; Liu, X.; Zhu, X-Guang., 2017: Altered expression profiles of microRNA families during de-etiolation of maize and rice leaves. MicroRNAs (miRNAs) are highly conserved small non-coding RNAs that play important regulatory roles in plants. Although many miRNA families are sequentially and functionally conserved across plant kingdoms (Dezulian et al. in Genome Biol 13, 2005),...

Haney, J.C.; Haury, L.R.; Mullineaux, L.S.; Fey, C.L., 1995: Sea-bird aggregation at a deep North Pacific seamount. During June 1991, we studied sea birds at a mid-ocean seamount (Fieberling Guyot) in the eastern North Pacific Ocean. Avifaunal composition changed from small Procellariiformes (a storm-petrel; Oceanodroma leucorhoa (Vieillot)) away from the seamo...

Haussen, D.C.; Bouslama, M.; Grossberg, J.A.; Anderson, A.; Belagage, S.; Frankel, M.; Bianchi, N.; Rebello, L.C.; Nogueira, R.G., 2016: Too good to intervene? Thrombectomy for large vessel occlusion strokes with minimal symptoms: an intention-to-treat analysis. The minimal stroke severity justifying endovascular intervention remains elusive; however, a significant proportion of patients presenting with large vessel occlusion (LVO) and mild symptoms subsequently decline and face poor outcomes. To evaluate...

Montero, A.; Booser, D.; Esparza-Guerra, L.; Murray, J.; Rosales, M.; Hortobagyi, G.; Valero, V., 2005: Phase I trial of dose-dense docetaxel and doxorubicin with or without sargramostim in patients with metastatic breast cancer. Drugs in R&d 6(5): 299-305

Zuber, M.X.; John, M.E.; Okamura, T.; Simpson, E.R.; Waterman, M.R., 1986: Bovine adrenocortical cytochrome P-450(17 alpha). Regulation of gene expression by ACTH and elucidation of primary sequence. In the steroidogenic pathway of the adrenal cortex, 17 alpha-hydroxylase cytochrome P-450 (P-450(17 alpha)) is a major regulatory enzyme. Previous studies have shown that stimulation of 17 alpha-hydroxylase activity occurs upon treatment of bovine...