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Preparation and photoinduced patterning of azidoformate-terminated self-assembled monolayers

, : Preparation and photoinduced patterning of azidoformate-terminated self-assembled monolayers. Langmuir 20(24): 10375-8

This paper presents a new method for the patterning of self-assembled monolayers (SAMs) using UV light. Azidoformate-terminated SAMs starting from 18-acetoxy-octadecyltrichlorosilane SAMs on silicon, prepared for the first time, are electrophilic and photosensitive, and can be patterned by UV irradiation through a mask. The resulting structured surfaces are still electrophilic and can be reacted with nucleophilic functions, for example, primary amines.


PMID: 15544361

DOI: 10.1021/la048080y

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