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A new enneanuclear nickel(II) cluster with a rectangular face-centered trigonal prism structure and cluster glass behavior

, : A new enneanuclear nickel(II) cluster with a rectangular face-centered trigonal prism structure and cluster glass behavior. Chemical Communications 48(7): 1015-1017

An enneanuclear nickel(II) complex with a rectangular face-centered trigonal prism structure bridged by μ(2)-pyrazolate, μ(6)-CO(3)(2-) and μ(3)-OH(-) groups was synthesized. It displays cluster glass-like magnetic behavior assigned to the single molecule magnet properties of {Ni(9)} clusters and weak intercluster interaction.


PMID: 22143156

DOI: 10.1039/c1cc16243h

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