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Bis(μ-2-{1-[2-(dimethyl-amino)-ethyl-imino]-eth-yl}phenolato)bis-[bromido-copper(II)] monohydrate

, : Bis(μ-2-{1-[2-(dimethyl-amino)-ethyl-imino]-eth-yl}phenolato)bis-[bromido-copper(II)] monohydrate. Acta Crystallographica. Section E, Structure Reports Online 67(Pt 7): M931-M931

In the centrosymmetric dinuclear copper(II) title complex, [Cu(2)Br(2)(C(12)H(17)N(2)O)(2)]·H(2)O, each Cu(II) ion is five coordinated in a square-pyramidal geometry by the N,N',O-tridentate Schiff base, one Br atom and the bridging O atom of the centrosymmetrically related Schiff base. In the crystal, the water mol-ecules link the complex mol-ecules into infinite chains along the b axis via O-H⋯Br and C-H⋯O hydrogen bonds.


PMID: 21836915

DOI: 10.1107/S1600536811022045

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