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Bis[(dimethyl-λ-sulfanyl-idene)oxonium] hexa-bromidotellurate(IV) dimethyl sulfoxide disolvate

, : Bis[(dimethyl-λ-sulfanyl-idene)oxonium] hexa-bromidotellurate(IV) dimethyl sulfoxide disolvate. Acta Crystallographica. Section E, Structure Reports Online 64(Pt 6): O1161-O1161

The structure of the title salt, 2C(2)H(7)OS(+)·Br(6)Te(2-)·2C(2)H(6)OS, displays O-H⋯O hydrogen bonding between one protonated dimethyl sulfoxide mol-ecule and a neighboring dimethyl sulfoxide mol-ecule, and an octa-hedral geometry for the Te atom; the latter is situated on a center of inversion.


PMID: 21202669

DOI: 10.1107/S1600536808015468

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