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Cationic complexes of silicon and germanium with (O,S)-chelate ligands

, : Cationic complexes of silicon and germanium with (O,S)-chelate ligands. Dalton Transactions 41(41): 12681-2

Synthesis and X-ray diffraction study of cationic bischelates MeSi(SCH(2)CONMe(2))(2)(+)Cl(-) and MeGe(SCH(2)CONMe(2))(2)(+)Br(-) are reported. According to X-ray data, the Si and Ge atoms in these compounds have distorted TBP environments with two coordinating oxygen atoms in axial positions.


PMID: 23007098

DOI: 10.1039/c2dt31554h

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