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Electron in the field of a molecule with an electric dipole moment


, : Electron in the field of a molecule with an electric dipole moment. Physical Review Letters 100(11): 110401-110401

In solving the eigenvalue wave equation, we relax the usual diagonal constraint on its matrix representation by allowing it to be tridiagonal. This results in a larger representation space that incorporates an analytic solution for the noncentral electric dipole pole potential cos theta/r2, which was believed not to belong to the class of exactly solvable potentials. Consequently, we obtain closed form solution of the time-independent Schrödinger equation for an electron in the field of a molecule treated as a point electric dipole.

US$19.90

PMID: 18517761

DOI: 10.1103/PhysRevLett.100.110401


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