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Increasing the dimensionality of cryogenic molecular coolers: Gd-based polymers and metal-organic frameworks

, : Increasing the dimensionality of cryogenic molecular coolers: Gd-based polymers and metal-organic frameworks. Chemical Communications 48(61): 7592-7594

The magnetothermal properties of a coordination polymer and a metal-organic framework (MOF) based on Gd(3+) ions are reported. An equally large cryogenic magnetocaloric effect (MCE) is found, irrespective of the dimensionality. This combined with their robustness makes them appealing for widespread magnetic refrigeration applications.


PMID: 22729217

DOI: 10.1039/c2cc33485b

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