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Localization and quantification of carbon-centered radicals on any amino acid of a protein

, : Localization and quantification of carbon-centered radicals on any amino acid of a protein. Analytical Chemistry 79(14): 5444-5448

A general strategy to localize and quantify carbon-centered radicals within proteins is described. The methodology was first exemplified on amino acids and then on a peptide. This method is applicable to any protein system regardless of size, and the site of hydrogen abstraction by *OH on all residues within proteins is easily and accurately detected.


PMID: 17579484

DOI: 10.1021/ac070751k

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