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Photoinduced electron transfers in zeolites: impact of the aluminum content on the activation energies

, : Photoinduced electron transfers in zeolites: impact of the aluminum content on the activation energies. Photochemical & Photobiological Sciences 11(10): 1515-1519

We report the activation energy determination corresponding to the recombination of the radical cation electron moiety created through photoionization of the 1,6-diphenyl-1,3,5-hexatriene molecule incorporated in ZSM-5 zeolite channels. We demonstrate that the charge separated state stabilization in zeolite does not depend only on the Al content but also on the Al repartition.


PMID: 22833151

DOI: 10.1039/c2pp25121c

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