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Quintet electronic states of N2


, : Quintet electronic states of N2. Journal of Chemical Physics 132(10): 104310-104310

We use large scale ab initio calculations to investigate the valence and valence-Rydberg quintet states of N(2), their transition moments and their spin-orbit couplings to the close lying triplet electronic states. In addition to the A' (5)Sigma(g)(+) and the C" (5)Pi(ui) states already known, we identify two weakly bound states (2 (5)Sigma(g)(+) and 2 (5)Pi(u)) at approximately 95,300 and 106,200 cm(-1) above N(2)(X (1)Sigma(g)(+), v=0). The other quintets are viewed to be repulsive in nature. Our potentials and couplings are used later to derive a set of accurate spectroscopic data for these quintets, their spin-orbit constants, and to elucidate the quintet-triplet dynamics and the role of these newly identified quintets for the production of cold atomic nitrogen.

US$19.90

PMID: 20232963

DOI: 10.1063/1.3359000


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Malhotra A.; Bhan A.; Hatcher V.B.; Sonnenblick E.H.; Scheuer J., 1977: Depressed myosin atpase activity in hearts of myopathic hamsters dissociation from neutral protease activity. Circulation Supplement 56(4): III-207

Maslova, M.N.; Tavrovskaya, T.V., 1996: Inhibition of sexual cycle in rodents. Protracted per os introduction of "Anaster" preparation, the derivative of carbon acids causes inhibitory effect to sexual activity of female rodents (rats, mice, hamsters) in particular, to the dynamics of sexual cycles and as a result...

Abe, K., 1984: Clinical and laboratory medicine in relation to medical education. Rinsho Byori. Japanese Journal of Clinical Pathology 32(1): 5-12

Hikita H., 1972: Electro physiological studies on the peristaltic propagation of the de nervated intestinal tract. Shikoku Acta Medica 28(1): 159-172

Dietrich, G.; Haupt, W.; Kretschmer, V., 1991: Disorders of primary hemostasis caused by albumin infusion in hemodilution. Previous studies using the In-vitro Bleeding Test have shown that albumin impairs primary hemostasis more pronouncedly than other infusion solutions. For this reason we compared ADP (4 microM)-induced platelet aggregation in samples of platelet ri...

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Etgens, V.H.; de Camargo, P.C.; Eddrief, M.; Mattana, R.; George, J.M.; Garreau, Y., 2004: Structure of ferromagnetic CrAs epilayers grown on GaAs(001). Magnetic and structural properties of CrAs epilayers grown on GaAs(001) by molecular beam epitaxy have been studied. CrAs epilayers are orthorhombic for all thicknesses investigated but show a structural transition from a metastable phase for very...

Vesolovskii, S., 1956: History of the development of urology in Poland. Urologiia 21(3): 53-56

Lee, Cs, 1978: Acetylation of s-triazine der. Han'guk Nonghwa Hakhoe chi = Journal of the Korean Agricultural Chemical Society 21(2): 119-122