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Synthesis of aza-fused polycyclic quinolines via double C-H bond activation


, : Synthesis of aza-fused polycyclic quinolines via double C-H bond activation. Chemistry 18(29): 8896-8900

Simple but efficient: Aza-fused polycyclic quinolines were efficiently assembled through rhodium(III)-based direct double C-H activation of N-aryl azoles followed by cyclization with alkynes without heteroatom-assisted chelation. Copper(II) acetate, aside from acting as an oxidant, could also play an important role in the C-H activation process.

US$19.90

PMID: 22715023

DOI: 10.1002/chem.201201207


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