geoscience.net logo
+ Resolve Article
+ Follow Us
Follow on FacebookFollow on Facebook
Follow on TwitterFollow on Twitter

+ Translate
+ Subscribe to Site Feed
GeoScience Most Shared ContentMost Shared Content

The role of an asymmetric nitride cluster on a fullerene cage: the non-IPR endohedral DySc2N@C76


, : The role of an asymmetric nitride cluster on a fullerene cage: the non-IPR endohedral DySc2N@C76. Journal of Physical Chemistry. B 111(49): 13659-13663

The first non-IPR C(76) cage based on a mixed metal nitride cluster, DySc(2)N@C(76), was successfully synthesized and isolated. DySc(2)N@C(76) is a stable fullerene with a small band gap of 0.96 eV. According to the FTIR spectroscopic study in combination with extensive DFT calculations, the cage structure of DySc(2)N@C(76) has been assigned to the non-IPR C(s): 17490-I isomer having two pairs of the adjacent pentagons. DySc(2)N@C(76)provides the first example of stabilization of the non-IPR C(76) cage by encapsulation of an asymmetric DySc(2)N mixed cluster, revealing the role of the cluster structure on the stability of the fullerene cage. As the asymmetric DySc(2)N cluster has a more suitable geometry for the inner space of the C(76) cage compared to that of the homogeneous clusters like Sc(3)N or Dy(3)N, the highest yield for C(76)-based cluster fullerenes with the Dy(x)Sc(3)-(x)N mixed nitride cluster is achieved for the DySc(2)N@C(76)

US$19.90

PMID: 18004840

DOI: 10.1021/jp709650d


Other references

Shroyer, M.C.; Griffin, R.L.; Mortellaro, V.E.; Russell, R.T., 2017: Massive transfusion in pediatric trauma: analysis of the National Trauma Databank. Massive transfusion (MT) in pediatric trauma has been described in combat populations and other single institutions studies. We aim to define the incidence of MT in a large US civilian pediatric trauma population, identify predictive parameters of...

Filhol, J., 1934: Sur les glandes annexes de l'oviducte chez Oxychilus lucidus Draparnaud. Compte Rendu des Seances de la Societe de Biologie Paris, 116: 1231-1233

Prystowsky, S.D.; Rogers, J.G., 1976: A median nodule of the upper lip as a familial trait. Oral Surgery, Oral Medicine, and Oral Pathology 42(5): 653-655

Ericsson, S.A.; Boice, M.L.; Funahashi, H.; Day, B.N., 1993: Assessment of porcine oocytes using brilliant cresyl blue. Theriogenology 39(1): 214

Abesadze G.E.; Vashadze E.S., 1969: Effect of the petroleum growth substance on grape d yield. Agrokhimiya (4): 89-93

Orkiszewski, P.; Pollitt, P.; Leonard, A.A.; Lane, S.Hayes., 2016: Using a Nursing History Web Site With Today's Nursing Students. Nurse Educator 40(6): 312-312

Ben-Ezra, M.; Aluf, D., 2006: Traumatic events v. life events: does it really matter?. British Journal of Psychiatry 188: 83-84

Lebedeva, V.S.; Soboleva, N.G., 1975: Physical rehabilitation of myo cardial infarction patients during the restorative period. In the in-patient rehabilitation department of the Leningrad cardiorheummatological dispensary 276 patients with large-focal and transmural myocardial infarction were kept under observation. The program of physical rehabilitation envisaged the emp...

Petzsch, H., 1955: Gesellschaftshaltung einer grosseren Anzahl von Iltissen (Putorius putorius ) und Frettchen (Putorius furo ) verechiedener Altersstufen. Zoologische Garten Leipzig, 21: 188-190

Imbeau, S.A.; Reed, C.E., 1979: Nylon stocking dermatitis. An unusual example. We report herein a woman sensitive to nylon stockings of only brown or tan shade. Her situation is interesting for several reasons: she does not react to paraphenylediamine and she reacts to red and yellow dyes, but not to blue or the finish; howe...