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Construction of an enterobactin analogue with symmetrically arranged monomer subunits of ferritin


, : Construction of an enterobactin analogue with symmetrically arranged monomer subunits of ferritin. Chemical Communications 51(93): 16609-16612

A set of three catecholamide ligands mimicking the structure of enterobactin was constructed on ferritin, where the 3-fold symmetric arrangement of the monomer subunits served as a foundation to form a coordination space. Similar to enterobactin, the ligands showed strong affinity for the ferric ion and formed a tris-catechoyl complex. Crystallography revealed that the complex was embedded in the entrance of the 3-fold axis channel.

US$19.90

PMID: 26404005

DOI: 10.1039/c5cc06904a


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