geoscience.net logo
+ Resolve Article
+ Follow Us
Follow on FacebookFollow on Facebook
Follow on TwitterFollow on Twitter

+ Translate
+ Subscribe to Site Feed
GeoScience Most Shared ContentMost Shared Content

Nitrite reduction by a pyridinediimine complex with a proton-responsive secondary coordination sphere


, : Nitrite reduction by a pyridinediimine complex with a proton-responsive secondary coordination sphere. Chemical Communications 52(73): 11016-9

The proton-responsive pyridinediimine ligand, (DEA)PDI (where (DEA)PDI = [(2,6-(i)PrC6H3)(N[double bond, length as m-dash]CMe)(N(Et)2C2H4)(N[double bond, length as m-dash]CMe)C5H3N]) was utilized for the reduction of NO2(-) to NO. Nitrite reduction is facilitated by the protonated secondary coordination sphere coupled with the ligand-based redox-active sites of [Fe(H(DEA)PDI)(CO)2](+) and results in the formation of the {Fe(NO)2}(9) DNIC, [Fe((DEA)PDI)(NO)2](+).

US$19.90

PMID: 27539064

DOI: 10.1039/c6cc05962g


Other references

Anupam Manna; Paul, A.K., 2000: Degradation of microbial polyester poly(3-hydroxybutyrate) in environmental samples and in culture. Poly(3-hydroxybutyrate) [P(3HB)] test-pieces prepared from the polymer produced by Azotobacter chroococcum were degraded in natural environments like soil, water, compost and sewage sludge incubated under laboratory conditions. Degradation in term...

Oostindie,K.; Dekker,L.W.; Wesseling,J.G.; Ritsema,C.J., 2008: Soil surfactant stops water repellency and preferential flow paths. This study reports the effects of a soil surfactant on reduction and prevention of water repellency and preferential flow paths in a sandy soil of a golf course fairway, located at Bosch en Duin near Utrecht, the Netherlands. The golf course is co...

Holzer, Z.; Levy, D., 1976: Poultry litter as a protein supplement for beef cattle fed fibrous diets. In the 3rd of 3 experiments to investigate the nutritional value of poultry litter for cattle, 15 lactating cows (3-4 wk post partum and aged 3-6 yr) were fed a basic ration of wheat straw ad lib., plus 2.5 kg ground sorghum grain (SG) during days...

Hughes, P.; Murdock, D.K.; Olson, K.; Juza, R.; Jenkins, K.; Wegner, A.; Hendricks, B., 2006: School children have leading risk factors for cardiovascular disease and diabetes: the Wausau SCHOOL project. Risk factors for cardiovascular disease and diabetes acquired in childhood commonly persist in later life and are particularly strong predictors of subclinical atherosclerosis in young adults. A rising tide of obesity and other lifestyle-related r...

Suarez Hernandez M.; Salcedo Rocha E.R.; Cruz D.P.z R.; Pina Moya R., 1991: Effectiveness of health education in the surveillance of rabies in mongooses. A program of sanitary education is implemented on the role of mongoose as a rabies reservoir in Ciego de Avila province starting from 1983. This paper compares the number of mongoose samples sent in and the positive cases of rabies in the 1977-198...

Choi, J-Kyoung.; Park, S-Yoon.; Kim, K.Hwan.; Park, S.Ra.; Lee, S-Geun.; Choi, B.Hyune., 2015: GM-CSF reduces expression of chondroitin sulfate proteoglycan (CSPG) core proteins in TGF-β-treated primary astrocytes. GM-CSF plays a role in the nervous system, particularly in cases of injury. A therapeutic effect of GM-CSF has been reported in rat models of various central nervous system injuries. We previously showed that GM-CSF could enhance long-term recover...

He, D-liang.; Yin, G-fu.; Dong, F-qin.; Liu, L-bao.; Luo, Y-jun., 2010: Research on the additives to reduce radioactive pollutants in the building materials containing fly ash. Several kinds of functional additives such as barite, zeolite, ferric oxide, gypsum, and high alumina cement were introduced to prepare a low-radiation cement-based composite to reduce radioactive pollutants contained in fly ash. The effect of con...

Damuth, J.E.; Nelson, C.H.ns; Olson, H.C.ement, 2008: Bryant Canyon/Fan and Rio Grande Fan turbidite systems; shelf to basin modern analogues for productive Tertiary mini-basin systems. The Western Ancestral Mississippi shelf-margin delta fed the Bryant Canyon/Fan Turbidite System primarily during the Marine Isotope Stage 6 glacial cycle. Multiple slope channels fed a chain of 15 fill and spill mini-basins with connecting canyons...

Mauger, S.J.; Warren, C.D.; Knight, M.R.; Goorevich, M.; Nel, E., 2015: Clinical evaluation of the Nucleus 6 cochlear implant system: performance improvements with SmartSound iQ. This paper provides a detailed description of the Nucleus 6 system, and clinically evaluates user performance compared to the previous Nucleus 5 system in cochlear implant recipients. Additionally, it clinically evaluates a range of Nucleus 6 and...

Klaus, W., 1978: On the taxonomic significance of tectum sculpture characters in alpine pinus species. SEM [scanning electron microscopy] investigation of pollen grain surfaces of 4 alpine Pinus spp. (P. sylvestris, P. mugo, P. uncinata and P. cembra) implies that tectum surface characters are less variable and more specific than other exine layers...