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Stereoselective cathodic synthesis of 8-substituted (1R,3R,4S)-menthylamines

, : Stereoselective cathodic synthesis of 8-substituted (1R,3R,4S)-menthylamines. Beilstein Journal of Organic Chemistry 11: 294-301

The electrochemical generation of menthylamines from the corresponding menthone oximes equipped with an additional substituent in position 8 is described. Due to 1,3-diaxial interactions a pronounced diastereoselectivity for the menthylamines is found.


PMID: 25815083

DOI: 10.3762/bjoc.11.34

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