+ Resolve Article
+ Follow Us
Follow on FacebookFollow on Facebook
Follow on TwitterFollow on Twitter

+ Translate
+ Subscribe to Site Feed
GeoScience Most Shared ContentMost Shared Content

Structural Induction Effect of a Zwitterion Pyridiniumolate for Metal-Organic Frameworks

, : Structural Induction Effect of a Zwitterion Pyridiniumolate for Metal-Organic Frameworks. Inorganic Chemistry 54(13): 6169-6175

It is still an enormous challenge to obtain the metal-organic frameworks (MOFs) with specific properties by tuning their structures. Here we first reported that the structures of MOFs could be tuned by adding certain amount of zwitterion pyridiniumolate. To demonstrate the inductive effect, two series of assembly experiments were performed using different metal ions, namely, Cd(II) and Mn(II). The experimental results revealed that the zwitterion pyridiniumloate only acted as a structural induction agent (SIA), which did not exist in the aimed compounds. The SIAs could effectively tune the framework aperture or promote coordination and further tune the properties of MOFs without any removal or exchange after the synthesis. Therefore, the results could not only immensely expand the syntheses and structural diversity of MOFs with the fixed metal ions and organic ligands but also afford the possibility and effective convenience for tuning the properties of MOFs in the functional material research fields.


PMID: 26046672

DOI: 10.1021/acs.inorgchem.5b00180

Other references

Shapiro, Alvin P., 1960: Effect of hypotensive drugs on the pressor response to noxious stimuli. Jour Clin Invest: 1028

Fortis P.A.; Pelis P.G.; Mapelli L., 1984: Surgical treatment of duodenal ulcer and medical therapy an evolving relationship. Rivista Generale Italiana di Chirurgia 35(3): 267-279

Vande Walle, J.G.J.; Van Aken, S.; Raes, A.; France, A.; Malfliet, F.; Craen, M., 1999: Monitoring and titrating lisinopril therapy in children. Journal of the American Society of Nephrology 10(PROGRAM AND ABSTR ISSUE): 135A, Sept

Chauvin, H.F., 1973: Trial of combined intermittent chemotherapy in prostatic cancers. Estrogen resistant metastases. Journal D'urologie et de Nephrologie 79(12 Pt 2): 397-398

Varani, K.; Abbracchio, M.P.; Cannella, M.; Cislaghi, G.; Giallonardo, P.; Mariotti, C.; Cattabriga, E.; Cattabeni, F.; Borea, P.Andrea.; Squitieri, F.; Cattaneo, E., 2003: Aberrant A2A receptor function in peripheral blood cells in Huntington's disease. A2A adenosine receptors specifically found on striatal medium spiny neurons play a major role in sensory motor function and may also be involved in neuropsychiatric and neurodegenerative disorders. One hypothesis concerning Huntington's disea...

Zapparoli, Marzio., 2005: New records on urban breeding pallid swift Apus pallidus in Rome Latium, Central Italy Nuovi dati sulla nidifacazione del rondone pallido Apus pallidus a Roma. Alula (Roma): 121-2: 254-256

Kitching, M.O.; Hurst, T.E.; Snieckus, V., 2012: Copper-catalyzed cross-coupling interrupted by an opportunistic Smiles rearrangement: an efficient domino approach to dibenzoxazepinones. Angewandte Chemie 51(12): 2925-2929

Abeck, D.; Börries, M.; Kuwert, C.; Steinkraus, V.; Vieluf, D.; Ring, J., 1994: Food-induced anaphylaxis in latex allergy. Contact uticaria and anaphylactic reactions to latex-containing rubber products are being recognized with increasing frequency in all kinds of medical disciplines. Recently a number of reports have been published describing anaphylactic reactions...

Evans, M.; Galloro, V., 2006: In good health, at least for now. Health systems report another strong year in 2005, but rising bad debt and concerns over reimbursement weigh on prognosis. Modern Healthcare 36(24): 24-6, 28-30

Storto, M.; de Grazia, U.; Knöpfel, T.; Canonico, P.L.; Copani, A.; Richelmi, P.; Nicoletti, F.; Vairetti, M., 2000: Selective blockade of mGlu5 metabotropic glutamate receptors protects rat hepatocytes against hypoxic damage. Western blot analysis of protein extracts from rat liver revealed the presence of the mGlu5 receptor, one of the G-protein-coupled receptors activated by glutamate (named "metabotropic glutamate receptors" or mGlu receptors). mGlu5 expre...